As it is obvious from its structure, allyl alcohol has the properties of both monohydric alcohol and olefin. Allyl alcohol is a propenol in which the cc bond connects c2 and c3. Methallyl alcohol appears as a colorless liquid with a sharp pungent odor. Allyl compounds comprise a large group of ethylenic compounds having unique reactivities and uses often contrasting with those of typical vinyl. Formerly used as a herbicide for the control of various grass and weed seeds. Methallyl alcohol c4h8o cid 10557 structure, chemical names, physical and chemical properties, classification, patents, literature. Allyl alcohol is an intermediate product in the production of glycerine, synthetic resins, and plastic materials.
Material safety data sheet allyl alcohol msds section no 1. First aid measures general advice consult a physician. In a controlled human sensory response study dunlap, kodama, wellington et al. Possibility of hazardous reactions hazardous polymerization may occur at elevated temperatures. Unlike monovinyl compounds, monoallyl compounds do not form homopolymers of high molecular weight by free. Converted to glycidol, it works as chemical intermediate in synthesis of esters, glycerol, glycidyl ethers, amines. Allyl alcohol article about allyl alcohol by the free.
Gasphase conversion of glycerol to allyl alcohol over. Sds of allyl alcohol, safety data sheets, cas 107186 chemblink. Allyl alcohol is converted mainly to glycidol, which is a chemical intermediate in the synthesis of glycerol, glycidyl ethers, esters, and amines. Allyl alcohol cas 107186, alcool allylique, vinyl carbinol. Allyl alcohol is used as a raw material for the production of glycerol, but is used as a precursor to many specialized compounds. The role of the crystalline phase of mo 3 vo x in the catalytic oxidation of allyl alcohol over four kinds of crystalline orthorhombic, trigonal, tetragonal, amorphous mo 3 vo x catalysts was investigated to determine the active sites for the reactions. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Use water spray, alcohol resistant foam, dry chemical or carbon dioxide. A practical determination of these hsp values would provide higher certainty. Both the growth and respiration of candida albicans are sensitive to extracts of allium sativum and investigations into the anticandidal activities are now focussing on the purified constituents to determine the targets of inhibition. Learn more about hansen solubility parameters hsp and their use in predictive formulation. Allyl iodide 3iodopropene is an organic halide used in synthesis of other organic compounds such as nalkyl 2pyrrolidones, sorbic acid esters, 5,5disubstituted barbituric acids, and organometallic catalysts.
Also, a variety of polymerizable esters are prepared from allyl alcohol, e. Pdf preparation and use of allyl alcohol in industrial. Allyl monomers and polymers dowbenko major reference. The invention discloses phenyl allyl alcohol polyether and a preparation method thereof.
Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed. Like many alcohols, it is a watersoluble, colourless liquid. The phenyl allyl alcohol polyether disclosed by the invention has an extremely good hydrophilic polyether structure and an extremely good oleophylic benzene ring structure. Firefighting measures suitable extinguishing media water spray, fog, co2, dry chemical, or alcohol resistant foam. Preparation and use of allyl alcohol in industrial organic synthesis. Sep 28, 2011 the most important adverse effects of occupational exposures to allyl alcohol are upperrespiratorytract irritation and burns of the eyes. Before 1985 traditional production methods required the alkaline hydrolysis of allyl chloride and the isomerization of propylene oxide. From propylene, two grades of allyl alcohol are produced. For bea catalyst under a 24 h catalytic test, the main reaction products were, as expected, acrolein, acetaldehyde and hydroxyacetone, with a minor amount of allyl alcohol and propionic aldehyde.
Citations are the number of other articles citing this article, calculated by crossref and updated daily. The top countries of suppliers are india, china, from which the percentage of allyl alcohol supply is 4%, 93% respectively. Allyl alcohol material safety data sheet cas no 107186. During fire, gases hazardous to health may be formed. Allyl alcohol and water can form an azeotrope with the minimum boiling point. Like many alcohols, it is a water soluble, colourless liquid, but it is more toxic than typical small alcohols. The catalytic conversion of glycerol to allyl alcohol under neat conditions is catalyzed by. Role of crystalline structure in allyl alcohol selective. Tell a friend about us, add a link to this page, or visit the webmasters page for free fun content. Allyl alcohol is a clear liquid that is used to produce a variety of derivatives and products.
Allyl alcohol 107186 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Us2739173a us305532a us30553252a us2739173a us 2739173 a us2739173 a us 2739173a us 305532 a us305532 a us 305532a us 30553252 a us30553252 a us 30553252a us 2739173 a us2739173 a us 2739173a authority us united states prior art keywords formic acid glycerin reaction allyl alcohol mixture prior art date 19520821 legal status the legal status. Allyl alcohol is also known by synonyms of 2propen1ol, vinylcarbinol, 2propenol, 2propenyl alcohol, allylic alcohol and comes with molecular formula of c3h6o and molecular weight of 58. Allyl alcohol and garlic allium sativum extract produce. The plant produces the alcohol by vaporphase oxidation of propylene to allyl acetate followed by liquidphase hydrolysis of the acetate to allyl alcohol. Allyl alcohol is an organic compound with the structural formula ch2chch2oh. The most important adverse effects of occupational exposures to allyl alcohol are upperrespiratorytract irritation and burns of the eyes.
Furfuryl alcohol material safety data sheet cas no 98. Properties safety and handling msds computational chemical data. Allyl alcohol, c3h5oh, earlier came into prominence as a toxic substance through the belief that its presence in wood alcohol methyl alcohol as an impurity largely accounted for the toxicity of the latter substance. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Special hazards arising from the substance or mixture fire hazard. Lacrimation tearing, blurred vision, and photophobia heightened sensitivity to light are common. Allyl alcohol may be present in natural methyl alcohol in such quantities as 0. Allyl alcohol c3h6o cid 7858 structure, chemical names, physical and chemical. Allyl iodide can be synthesized from allyl alcohol and methyl iodide on. Allyl alcohol is mostly used for synthetic fragrancis, pharmaceutical intermediates, allyl ester resins and high performance cross link agents. Toxicometric parameters of industrial toxic chemicals under single exposure. It is the raw material for the synthesis of a wide range of allylic derivatives such as allyl diglycol carbonate, allyl glycidyl ether, 1,4butanediol, poly styrene allyl alcohol, etc.
Allyl alcohol material safety data sheet cas no 10718. Us2838575a production of glycerine by hydroxylation of. It should be noted that the selectivity of allyl alcohol never exceeds 2% in these conditions. Hazard statements h225 highly flammable liquid and vapour. Allyl alcohol, gstp, initiation, cyp2e1, rat, liver. We ask that users who download significant portions of the database cite the hmdb paper in any. These metrics are regularly updated to reflect usage leading up to the last few days. Sigmaaldrich offers a number of allyl alcohol products. It is an extremely hazardous substance, can cause severe irritation and must be handled with extreme caution. Allyl alcohol aa, the focus of the present study, is produced from garlic in two ways. Prior art keywords hydrogen peroxide reaction glycerine allyl alcohol catalyst prior art date 19560503 legal status the legal status is an assumption and is not a legal conclusion.
These listed allyl alcohol companies offer top quality products. Of particular interest is allyl alcohol aa, a metabolic product that accumulates after trituration of garlic cloves. Allyl alcohol is an industrially important olefinic alcohol. In larger amounts, the odor is pungent and mustardlike. Reactions of allyl alcohol1c14 journal of the american. It has a role as an insecticide, a herbicide, an antibacterial agent, a fungicide and a plant metabolite. Moderately toxic by ingestion and is an irritant to.
Use alcohol resistant foam, carbon dioxide, water, or dry chemical spray. Allyl isothiocyanate, stabilized revision date 08mar2019 component casno weight % allyl isothiocyanate 57067 allyl alcohol itself, when reacted with iodobenzene and triethylamine, with palladium acetate as catalyst, for example, produces a 71% yield of an 84. Signs and symptoms of acute allyl alcohol exposure. Tetragonal mo 3 vo x was found less active for the formation of acrylic acid from allyl alcohol, although acrolein was.
These derivatives find application as lens, coupling agents, plasticizers, crosslinking agents and. Unsuitable extinguishing a solid water stream may be inefficient. Find database of allyl alcohol cas no 107186 manufacturers, allyl alcohol suppliers, exporters. This list of compatible products is generated out of estimated hsp values.
Allyl bromide cas no 106956 material safety data sheet sdsmsds. Home cas database listed 2 styrene allyl alcohol copolymer material safety data sheetmsds cas no. Sds of allyl alcohol, safety data sheets, cas 107186. Studies of allyl alcohol radical polymerization by pfghmqc. Show this safety data sheet to the doctor in attendance. Allyl chloride safety data sheet 06252015 en english us sds id. Moderately toxic by ingestion and is an irritant to eyes and skin. Allyl alcohol is an unsaturated alcohol of the simplest structure, but chemically it is relatively stable and does not cause radical reaction by light, air, acid, alkali, etc. Article views are the countercompliant sum of full text article downloads since november 2008 both pdf and html across all institutions and individuals. Material safety data sheet msds caustic soda section 1. Thanks to its very low level of npropanol residual max 0.
Showa denko has been manufacturing allyl alcohol with a unique, more energy efficient process since 1985. Catalyzed allylation of alkynes with allyl alcohol in aqueous media. Fire fighting measures flammable properties the product is flammable, and heating may generate vapours which may form explosive vapourair mixtures. The effects of allyl alcoholinduced cell proliferation for detection of.
Signs and symptoms of acute exposure to allyl alcohol may be severe and include eye and skin irritation, pain, burns, and ulceration. Studies of allyl alcohol radical polymerization by pfg. Allyl alcohol cas no 107186 manufacturers, suppliers. Material safety data sheet allyl alcohol msds finar limited. Allyl alcohol is the smallest representative of the allylic alcohols. Showa denko has recently completed construction of an allyl alcohol plant at its oita complex in japan.
Allyl bromide material safety data sheet cas no 106. Find msds or sds, a coa, data sheets and more information. If inhaled if breathed in, move person into fresh air. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. After the allylic hydrogen abstraction by initiator radicals, allyl radicals produce chain ends with vinyl groups and aldehyde groups.
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